First-Order Chemistry in the Surface-Flux Layer     

L. Kristensen  C. E. Andersen  H. E. Jørgensen  P. Kirkegaard  K. Pilegaard 《Journal of Atmospheric Chemistry》1997,27(3):249-269

We have discussed the behavior of a non-conserved scalar in the stationary, horizontally homogeneous, neutral surface-flux layer and, on the basis of conventional second-order closure, derived analytic expressions for flux and for mean concentration of a gas, subjected to a first-order removal process. The analytic flux solution showed a clear deviation from the constant flux, characterizing a conserved scalar in the surface-flux layer. It decreases with height and is reduced by an order of magnitude of the surface flux at a height equal to about the typical mean distance a molecule can travel before destruction. The predicted mean concentration profile, however, shows only a small deviation from the logarithmic behavior of a conserved scalar. The solution is consistent with assuming a flux-gradient relationship with a turbulent diffusivity corrected by the Damköhler ratio, the ratio of a characteristic turbulent time scale and the scalar mean lifetime. We show that if we use only first-order closure and neglect the effect of the Damköhler ratio on the turbulent diffusivity we obtain another analytic solution for the profiles of the flux and the mean concentration which, from an experimental point of view, is indistinguishable from the first analytic solution. We have discussed two cases where the model should apply, namely NO which, by night, is irreversibly destroyed by interaction with mainly O₃ and the radioactive ²²⁰Rn. Only in the last case was it possible to find data to shed light on the validity of our predictions. The agreement seemed such that a falsification of our model was impossible. It is shown how the model can be used to predict the surface flux of ²²⁰Rn from measured concentration profiles.  相似文献   

AN EVALUATION OF SEVERAL TURBULENCE SCHEMES FOR THE PREDICTION OF MEAN AND TURBULENT FIELDS IN COMPLEX TERRAIN   总被引：2，自引：0，他引：2  

PETER J. HURLEY 《Boundary-Layer Meteorology》1997,83(1):43-73

A prognostic three-dimensional mesoscale model has been developed andused in one- and two-dimensional modes to evaluate ten local turbulenceclosure schemes. The schemes ranged from first-order to the two-equationprognostic schemes. Predictions by the models were compared for aone-dimensional convective boundary layer using mixed layer scaling andmeasurements to interpret the results. Two-dimensional simulations were alsoperformed for a sea-breeze flow and for flow over a hill. The results showedthat for all of the models considered, minor differences were produced in themean meteorological fields and in the vertical scalar fluxes, but majordifferences were apparent in the velocity variances and dissipation rate.Predicted tracer concentrations were very sensitive to the turbulence modelformulation for dispersion from a point source in the convective boundarylayer, particularly for the prediction of maximum concentrations. Predictedtracer concentrations from a surface volume source for the two-dimensionalsimulations were similar for all models, although the degree of mixing in themorning growth period produced some differences. Generally, good results forthe mean meteorological fields can be obtained with first-order schemes, evenif they underpredict the magnitude of turbulence in the convective boundarylayer, and reasonable tracer concentrations can also be obtained with thesemodels provided near-source effects are not important. The two-equationprognostic models performed best for the prediction of turbulence in theconvective boundary layer.  相似文献   

On the Spatial Distribution and Seasonal Variation of Lower-Troposphere Ozone over Europe     

H. E. Scheel  H. Areskoug  H. Geiss  B. Gomiscek  K. Granby  L. Haszpra  L. Klasinc  D. Kley  T. Laurila  A. Lindskog  M. Roemer  R. Schmitt  P. Simmonds  S. Solberg  G. Toupance 《Journal of Atmospheric Chemistry》1997,28(1-3):11-28

Surface ozone data from 25 Europeanlow-altitude sites and mountain sites located between79°N and 28°N were studied. The analysiscovered the time period March 1989–February 1993.Average summer and winter O₃ concentrations inthe boundary layer over the continent gave rise togradients that were strongest in the north-west tosouth-east direction and west-east direction, respectively. WintertimeO₃ ranged from 19 to 27 ppbover the continent, compared to about 32 ppb at thewestern border, while for summer the continentalO₃ values ranged between 39 and 56 ppb and theoceanic mixing ratios were around 37 ppb. In the lowerfree troposphere average wintertime O₃ mixingratios were around 38 ppb, with only an 8 ppbdifference between 28°N and 79°N. For summerthe average O₃ levels decreased from about 55 ppbover Central Europe to 32 ppb at 79°N. Inaddition, O₃ and O_x(= O₃ + NO₂)in polluted and clean air were compared. Theamplitudes of the seasonal ozone variations increasedin the north-west to south-east direction, while thetime of the annual maximum was shifted from spring (atthe northerly sites) to late summer (at sites inAustria and Hungary), which reflected the contributionof photochemical ozone production in the lower partsof the troposphere.  相似文献   

CLIMATIC RECORDS FROM ANNUAL LAYERS AND STABLE ISOTOPES OF A STALAGMITE IN BEIJING OVER THE LAST 2300 YEARS     

Tan Ming Qin Xiaoguang Liu Tungsheng Laboratory of Speleothem  Paleoclimatology  Institute of Geology  CAS  Beijing People’s Republic of China 《地理学报(英文版)》1997,(3)

Ｉ.ＩｎｔｒｏｄｕｃｔｉｏｎＳｔａｌａｇｍｉｔｅｓｈａｖｅｂｅｅｎａｐｐｌｉｅｄｔｏｕｓｅａｓｈｉｇｈｒｅｓｏｌｕｔｉｏｎｐａｌｅｏｃｌｉｍａｔｉｃｉｎｄｉｃａｔｏｒｓｓｉｎｃｅｔｈｅａｎｎｕａｌｇｒｏｗｔｈｂａｎｄｉｎｇｗａｓｒｅｃｏｇｎｉｚｅｄｉｎｓｔａｌａｇｍｉｔｅｓ[1,2].Ａｎｎｕａｌｇｒｏｗｔｈｂａｎｄｉｎｇｃａｎｂｅｍａｎｉｆｅｓｔｅｄｉｎｓｅｖｅｒａｌｍａｎｎｅｒｓｄｅｆｉｎｅｄｂｙ1)ａｌｔｅｒｎａｔｉｎｇｆｌｕｏｒｅｓｃｅｎｔａｎｄｎｏｎ-ｆｌｕｏｒｅｓｃｅｎｔｃａｌｃｉｔｅ[3,4];2)…  相似文献   

中国北部边疆第四系地下水研究     

李国安  韩朝平 《第四纪研究》1996,16(2):105-114

在中国北部边疆西起天山东端的北山，东至大兴安岭北段的４２００ｋｍ地域内，气候干旱少雨，水资源贫乏，第四系地下水是主要供水源之一。本文首次比较系统地研究了该区第四纪堆积物的分布和地下水的赋存规律。文中依据不同地貌单元、地层岩性及气候条件诸因素将本区第四系地下水划分为枝状沟谷砂砾石层孔隙水、河谷冲积平原砂砾石层孔隙水两种主要类型，并着重对有重要供水意义的河谷冲积平原砂砾石层孔隙水的分布、埋藏条件、富水性及水化学特征进行了论述。  相似文献   

天山地震活动区的深部构造特征   总被引：1，自引：0，他引：1  

胥颐 《新疆地质》1996,(2)

以地壳介质的Ｐ波速度分布和导电性为基础，描述了天山地区几个主要地震活动区域深部构造特征，地震大都发生在地壳内不同速度块体之间的过渡带附近；沿着天山的南缘和毗邻塔里木盆地的西昆仑、阿尔金等山前地带，壳内高导层由北向南、由东向西逐渐加深并增厚，它们与所在地区震源深度的分相相吻合。这种不稳定的地壳结构有长期受力情况下非常容易发生形变甚至破裂而引发地震。  相似文献   

鲁西地壳隆升的伸展构造模式   总被引：23，自引：2，他引：23  

燕守勋 《地质学报》1996,70(1):1-11

伸展链锁断层系，形成了鲁西的主导造格局，即“块断”构造。它是由中、生代两次伸展运动形成的。伸展运动幔源岩浆活动有着密切的成生联系。伸展运动的结果，形成了以泰山－鲁山－沂山为核心的鲁中块隆，它至今耸立于周围以平原地貌为标志的地堑系之间，隆起的高点，就是当今的泰山。  相似文献   

大陆层控构造论盆－山系与造山带成因及演化新模式   总被引：1，自引：0，他引：1  

李扬鉴  张星亮 《化工矿产地质》1996,18(3):149-155

大陆构造以受中地壳塑性层控制的盆－山系和冲叠造山带厚皮构造为主要构造类型，而与中生代以来才出现的受软流层控制的大洋岩石圈板块构造截然不同。由上地壳正断层上盘断陷盆地和下盘断隆山所组成的盆－山系，与地球自转速度逐渐变慢派生不同性质水平力和重力的共同作用有关。当地球自转速度突然变化时，将派生强烈的侧压力，使升降幅度较大、具有侧向应变空间的断陷盆地与断隆山之间的上地壳发生冲叠运动，盆－山系由此演变成冲叠造山带。后者对前者存在着严格的继承关系，服从于“升降－冲叠律”。中生代以来的盆－山系和冲叠造山带有的是板块活动产物  相似文献   

气相色谱和薄层色谱法在形态分析中的应用   总被引：2，自引：0，他引：2  

方国桢  方梅 《岩矿测试》1996,15(4):299-310

评述了气相色谱和薄层色谱法用于氯、溴、碘、硫、硒、碲、铬、氮、磷、砷、钒、碳、锡、铅、铁和汞１６种元素的不同形态分析的进展。这些形态包括不同价态、有机态、无机态、阳离子和阴离子态等。由于气相色谱和薄层色谱法都具有分离和检测两种功能结合的特点，因此它们是用于元素形态分析的有效和方便的方法。引用１９８０～１９９４年文献９２篇  相似文献   

多波资料综合解释方法研究的若干进展   总被引：9，自引：0，他引：9  

贺振华  何樵登 《矿物岩石》1997,17(4):76-93

本文较系统地总结了多波层位识别的主要原则和方法；提出了利用井中纵、横波速度求取地层密度、孔隙度的改进方法；研制了以小波分解与重建为基础的沿层分频处理法和高分辨剖面重建方法，提高了薄层识别的横向和纵向分辨率；发展了精度高、误差小计算薄层速度的补层加权法；介绍了各向异性介质参数反演的遗传算法，走时法以及Ｐ－ＳＶ波ＡＶＯ分析等方法；建立了多波解释系统的总体框架。所提方法的有效性和正确性均经过实际地震记录和数值模拟计算的检验，对丰富多波地震资料的解释理论，形成多波解释系统，扩大应用领域，提高应用效果具有重要参考意义。  相似文献